(M)SDS Format : ------------------------------------------------------------------------ MSDS ------------------------------------------------------------------------ *View (M)SDS Section : * *1* <#section1> *2* <#section2> *3* <#section3> *4* <#section4> *5* <#section5> *6* <#section6> *7* <#section7> *8* <#section8> *9* <#section9> *10* <#section10> *11* <#section11> *12* <#section12> *13* <#section13> *14* <#section14> *15* <#section15> *16* <#section16> ------------------------------------------------------------------------ *SAFETY DATA SHEET * ------------------------------------------------------------------------ SECTION 1 : IDENTIFICATION ------------------------------------------------------------------------ _Product identifier used on the label: _ Product Name: *Prelude * _Other means of identification: _ _Recommended use of the chemical and restrictions on use: _ _Chemical manufacturer address and telephone number: _ Manufacturer Name: Perma-Chink Systems, Inc. Address: 1605 Prosser Road Knoxville, TN 37914 USA Website: www.permachink.com General Phone Number: 800-548-3554 General Fax Number: 865-523-9475 Customer Service Phone Number: 865-524-7343 _Emergency phone number: _ Emergency Phone Number: CHEMTREC 1-800-424-9300 ------------------------------------------------------------------------ SECTION 2 : HAZARD(S) IDENTIFICATION ------------------------------------------------------------------------ _Classification of the chemical in accordance with CFR 1910.1200(d)(f): _ Signal Word: Not applicable. GHS Class: Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.. Hazard Statements: Not applicable. Precautionary Statements: Not applicable. _Hazards not otherwise classified that have been identified during the classification process: _ Potential Health Effects: Eye: Causes eye irritation. Skin: Causes skin irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: May be harmful if swallowed. May cause vomiting. Chronic Health Effects: Prolonged or repeated contact may cause skin irritation. Signs/Symptoms: Overexposure may cause headaches and dizziness. Target Organs: Eyes. Skin. Respiratory system. Digestive system. Aggravation of Pre-Existing Conditions: None generally recognized. ------------------------------------------------------------------------ SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS ------------------------------------------------------------------------ _Mixtures: _ *Chemical Name * *CAS#* *Ingredient Percent* *EC Num. * ------------------------------------------------------------------------ Amorphous silicon dioxide, chemically prepared 7631-86-9 0.5 - 1.0 by weight 231-545-4 Propylene glycol 57-55-6 2 - 3 by weight 200-338-0 ------------------------------------------------------------------------ SECTION 4 : FIRST AID MEASURES ------------------------------------------------------------------------ _Description of necessary measures: _ Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Remove contacts if present and easy to do. Continue rinsing. Get medical attention, if irritation or symptoms of overexposure persists. Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. ------------------------------------------------------------------------ SECTION 5 : FIRE FIGHTING MEASURES ------------------------------------------------------------------------ _Suitable and unsuitable extinguishing media: _ Suitable Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry chemical, or water fog or spray when fighting fires involving this material. _Special protective equipment and precautions for fire-fighters: _ Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. *_NFPA Ratings_:* NFPA Health: 1 NFPA Flammability: 1 NFPA Reactivity: 0 1 10 ------------------------------------------------------------------------ SECTION 6 : ACCIDENTAL RELEASE MEASURES ------------------------------------------------------------------------ _Personal precautions, protective equipment and emergency procedures: _ Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Use proper personal protective equipment as listed in Section 8. _Environmental precautions: _ Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. _Methods and materials for containment and cleaning up: _ Methods for containment: Contain spills with an inert absorbent material such as soil or sand. Prevent from spreading by covering, diking or other means. Provide ventilation. Methods for cleanup: Clean up spills immediately observing precautions in the protective equipment section. Place into a suitable container for disposal. Provide ventilation. After removal, flush spill area with soap and water to remove trace residue. ------------------------------------------------------------------------ SECTION 7 : HANDLING and STORAGE ------------------------------------------------------------------------ _Precautions for safe handling: _ Handling: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or mist. _Conditions for safe storage, including any incompatibilities: _ Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly closed when not in use. ------------------------------------------------------------------------ SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION ------------------------------------------------------------------------ _EXPOSURE GUIDELINES: _ _Appropriate engineering controls: _ Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. _Individual protection measures: _ Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. PPE Pictograms: ------------------------------------------------------------------------ SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES ------------------------------------------------------------------------ _PHYSICAL AND CHEMICAL PROPERTIES: _ Physical State: Liquid. Physical State Appearance: Liquid Color: Off White Odor: Slight latex odor Odor Threshold: No Data Boiling Point: 212°F Melting Point: No Data Density: 8.40 - 8.65 lb./gal Specific Gravity: 1.02 - 1.04 Specific Volume: No Data Solubility: No Data Vapor Density: No Data Vapor Pressure: No Data Percent Volatile: 79 - 82 Evaporation Rate: No Data Evaporation Point: No Data pH: 8.0 - 8.5 Molecular Formula: Mixture Molecular Weight: Not applicable. Viscosity: 250 - 300 cP Coefficient of Water/Oil Distribution: No Data Flammability: No Data Flash Point: No Data Lower Flammable/Explosive Limit: Not applicable. Upper Flammable/Explosive Limit: Not applicable. Explosive Properties: No Data Oxidizing Properties: No Data Refractive Index: No Data Optical Rotation: No Data VOC Content: < 200 g/L (Less Water) ------------------------------------------------------------------------ SECTION 10 : STABILITY and REACTIVITY ------------------------------------------------------------------------ _Chemical Stability: _ Chemical Stability: Stable under normal temperatures and pressures. _Possibility of hazardous reactions: _ Hazardous Polymerization: Not reported. _Conditions To Avoid: _ Conditions to Avoid: Heat, flames, incompatible materials, and freezing or temperatures below 32 deg. F. _Incompatible Materials: _ Incompatible Materials: Oxidizing agents. Strong acids and alkalis. ------------------------------------------------------------------------ SECTION 11 : TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ _TOXICOLOGICAL INFORMATION: _ *_Amorphous silicon dioxide, chemically prepared _:* Eye: Administration into the eye - Rabbit Standard Draize test: 25 mg/24H [Mild] (RTECS) *_Propylene glycol _:* Eye: Administration into the eye - Rabbit Standard Draize test: 100 mg [Mild] Administration into the eye - Rabbit Standard Draize test: 500 mg/24H [Mild] (RTECS) Skin: Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: 20800 mg/kg [Details of toxic effects not reported other than lethal dose value] Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill: 20800 mg/kg [Behavioral - Ataxia Behavioral - Tetany Lungs, Thorax, or Respiration - Respiratory depression] (RTECS) Ingestion: Oral - Rat LD50 - Lethal dose, 50 percent kill: 20 gm/kg [Details of toxic effects not reported other than lethal dose value] (RTECS) ------------------------------------------------------------------------ SECTION 12 : ECOLOGICAL INFORMATION ------------------------------------------------------------------------ _Ecotoxicity: _ Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. ------------------------------------------------------------------------ SECTION 13 : DISPOSAL CONSIDERATIONS ------------------------------------------------------------------------ _Description of waste: _ Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. ------------------------------------------------------------------------ SECTION 14 : TRANSPORT INFORMATION ------------------------------------------------------------------------ DOT Shipping Name: Not restricted as a dangerous good. DOT UN Number: Not restricted as a dangerous good. IATA Shipping Name: Not restricted as a dangerous good. IATA UN Number: Not restricted as a dangerous good. Canadian Shipping Name: Not restricted as a dangerous good. Canadian UN Number: Not restricted as a dangerous good. IMDG UN Number : Not restricted as a dangerous good. IMDG Shipping Name : Not restricted as a dangerous good. ADR UN Number: Not restricted as a dangerous good. ADR Shipping Name : Not restricted as a dangerous good. ------------------------------------------------------------------------ SECTION 15 : REGULATORY INFORMATION ------------------------------------------------------------------------ _Safety, health and environmental regulations specific for the product: _ *_Amorphous silicon dioxide, chemically prepared _:* TSCA Inventory Status: Listed Canada DSL: Listed EC Number: 231-545-4 *_Propylene glycol _:* TSCA Inventory Status: Listed Canada DSL: Listed EC Number: 200-338-0 ------------------------------------------------------------------------ SECTION 16 : ADDITIONAL INFORMATION ------------------------------------------------------------------------ _HMIS Ratings_: HMIS Health Hazard: 1 HMIS Fire Hazard: 1 HMIS Reactivity: 0 HMIS Personal Protection: X *Health Hazard* * 1* *Fire Hazard* * 1* *Reactivity* * 0* *Personal Protection* * X* SDS Creation Date: July 30, 2015 SDS Revision Date: November 02, 2015 SDS Format: SDS Author: Actio Corporation Disclaimer: The information contained herein is, to the best of Perma-Chink Systems, Inc. knowledge, accurate as of the data indicated. Since the information contained herein may be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume responsibility for the results of its use. This information is furnished on the condition that the person receiving it shall make his own determination as to the suitability of the material for his particular purpose and on the condition that he assumes the risk of his use thereof. Copyright© 1996-2015 Actio Corporation. All Rights Reserved.